Offshore green ammonia synthesis
Nature Synthesis (2023)Cite this article
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The global potential for renewable energy production far exceeds global energy demand. However, the accessibility of renewable energy is constrained by existing land use, the need to preserve protected areas and the costs associated with transporting energy over large distances. As a consequence, finite renewable energy capacity must be carefully matched to appropriate end uses. In this Perspective, we advocate the production of green ammonia on the ocean to address this policy challenge: local renewables should be used to generate electricity with high efficiency, whereas comparatively low-efficiency chemical energy storage in the form of ammonia should occur further away from energy consumers and be transported at relatively low costs. We describe the synthesis processes to be adopted, the techno-economic basis for this resource allocation, and the technical developments required that can enable this energy system to be established.
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Oil and Petroleum Products Explained (US Energy Information Administration, 2022); https://www.eia.gov/energyexplained/oil-and-petroleum-products/imports-and-exports.php
Carter, L., Quicke, A. & Armistead, A. Over a Barrel: Addressing Australia's Liquid Fuel Security (The Australia Institute, 2022); https://australiainstitute.org.au/wp-content/uploads/2022/04/P1036-Over-a-barrel_liquid-fuel-security-WEB.pdf
Devlin, A. & Yang, A. Regional supply chains for decarbonising steel: energy efficiency and green premium mitigation. Energy Convers. Manage. 254, 115268 (2022).
Article CAS Google Scholar
Hydrogen: A Renewable Energy Perspective (International Renewable Energy Agency, 2019); https://www.irena.org/publications/2019/Sep/Hydrogen-A-renewable-energy-perspective
Cesaro, Z. The Role of Green Ammonia in Sector Coupling and Seasonal Electricity Storage (Univ. Oxford, 2021); https://www.ammoniaenergy.org/wp-content/uploads/2021/11/20211105_ZCesaro_AEAConference_noappendix.pdf
Innovation Outlook: Renewable Ammonia (International Renewable Energy Agency & Ammonia Energy Association, 2022).
Navigating the Way to a Renewable Future: Solutions to Decarbonise Shipping. Preliminary Findings (International Renewable Energy Agency, 2019); https://www.irena.org/publications/2019/Sep/Navigating-the-way-to-a-renewable-future
Valera-Medina, A., Xiao, H., Owen-Jones, M., David, W. I. F. & Bowen, P. J. Ammonia for power. Prog. Energy Combust. Sci. 69, 63–102 (2018).
Article Google Scholar
Renewable Energy Hub in Australia (British Petroleum, 2023); https://www.bp.com/en_au/australia/home/who-we-are/reimagining-energy/decarbonizing-australias-energy-system/renewable-energy-hub-in-australia.html
Moriarty, P. & Honnery, D. What is the global potential for renewable energy. Renew. Sustain. Energy Rev. 16, 244–252 (2012).
Article Google Scholar
Deng, Y. Y. et al. Quantifying a realistic, worldwide wind and solar electricity supply. Glob. Environ. Change 31, 239–252 (2015).
Article Google Scholar
Windemer, R. Considering time in land use planning: an assessment of end-of-life decision making for commercially managed onshore wind schemes. Land Use Policy 87, 104024 (2019).
Article Google Scholar
Katsouris, G. & Marina, A. Cost Modelling of Floating Wind Farms (ECN, 2016); https://questfwe.com/wp-content/uploads/2018/02/Cost-Modeling-of-Floating-Wind-Farms-ECN-2016.pdf
Feldman, D. et al. U.S. Solar Photovoltaic System and Energy Storage Cost Benchmark: Q1 2020 (National Renewable Energy Laboratory, 2021); https://www.nrel.gov/docs/fy21osti/77324.pdf
Dugger, G. L. & Francis, E. J. Design of an ocean thermal energy plant ship to produce ammonia via hydrogen. Int. J. Hydrog. Energy 2, 231–249 (1977).
Article CAS Google Scholar
Wang, H., Daoutidis, P. & Zhang, Q. Harnessing the wind power of the ocean with green offshore ammonia. ACS Sustain. Chem. Eng. 9, 14605–14617 (2021).
Article CAS Google Scholar
Salmon, N. & Bañares-Alcántara, R. Impact of grid connectivity on cost and location of green ammonia production: Australia as a case study. Energy Environ. Sci. 14, 6655–6671 (2021).
Article Google Scholar
Beerbühl, S. S., Fröhling, M. & Schultmann, F. Combined scheduling and capacity planning of electricity-based ammonia production to integrate renewable energies. Eur. J. Oper. Res. 241, 851–862 (2015).
Article Google Scholar
Nayak-Luke, R. & Bañares-Alcántara, R. Techno-economic viability of islanded green ammonia as a carbon-free energy vector and as a substitute for conventional production. Energy Environ. Sci. 13, 2957–2966 (2020).
Article CAS Google Scholar
Cheema, I. I. & Krewer, U. Operating envelope of Haber–Bosch process design for power-to-ammonia. RSC Adv. 8, 34926–34936 (2018).
Article CAS PubMed PubMed Central Google Scholar
Smith, C., Hill, A. K. & Torrente-Murciano, L. Current and future role of Haber–Bosch ammonia in a carbon-free energy landscape. Energy Environ. Sci. 13, 331–344 (2020).
Article Google Scholar
Humphreys, J., Lan, R. & Tao, S. Development and recent progress on ammonia synthesis catalysts for Haber–Bosch process. Adv. Energy Sustain. Res. 2, 2000043 (2021).
Article CAS Google Scholar
Smith, C. & Torrente-Murciano, L. Exceeding single-pass equilibrium with integrated absorption separation for ammonia synthesis using renewable energy—redefining the Haber–Bosch loop. Adv. Energy Mater. 11, 2003845 (2021).
Article CAS Google Scholar
MacFarlane, D. R. et al. A roadmap to the ammonia economy. Joule 4, 1186–1205 (2020).
Article CAS Google Scholar
Ahluwalia, R. K., Papadias, D. D., Peng, J.-K. & Roh, H. S. System Level Analysis of Hydrogen Storage Options (Argonne National Laboratory, 2019); https://www.hydrogen.energy.gov/pdfs/review19/st001_ahluwalia_2019_o.pdf
Salmon, N. & Bañares-Alcántara, R. in Computer Aided Chemical Engineering Vol. 49 (eds Yamashita, Y. & Kano, M.) 1903–1908 (Elsevier, 2022).
Fasihi, M., Weiss, R., Savolainen, J. & Breyer, C. Global potential of green ammonia based on hybrid PV-wind power plants. Appl. Energy 294, 116170 (2021).
Article CAS Google Scholar
James, B., Houchins, C., Huya-Kouadio, J. M. & DeSantis, D. A. Final report: hydrogen storage system cost analysis. OSTI.GOV https://www.osti.gov/servlets/purl/1343975 (2016).
Bellosta Von Colbe, J. et al. Application of hydrides in hydrogen storage and compression: achievements, outlook and perspectives. Int. J. Hydrog. Energy 44, 7780–7808 (2019).
Article CAS Google Scholar
Salmon, N., Bañares-Alcántara, R. & Nayak-Luke, R. Optimization of green ammonia distribution systems for intercontinental energy transport. iScience 24, 102903 (2021).
Article CAS PubMed PubMed Central Google Scholar
Shatat, M. & Riffat, S. B. Water desalination technologies utilizing conventional and renewable energy sources. Int. J. Low Carbon Technol. 9, 1–19 (2014).
Article Google Scholar
Salmon, N. & Bañares-Alcántara, R. Green ammonia as a spatial energy vector: a review. Sustain. Energy Fuels 5, 2814–2839 (2021).
Article CAS Google Scholar
Alkaisi, A., Mossad, R. & Sharifian-Barforoush, A. A review of the water desalination systems integrated with renewable energy. Energy Procedia 110, 268–274 (2017).
Article Google Scholar
Curto, D., Franzitta, V. & Guercio, A. A review of the water desalination technologies.Appl. Sci. 11, 670 (2021).
Article CAS Google Scholar
Do Thi, H. T., Pasztor, T., Fozer, D., Manenti, F. & Toth, A. J. Comparison of desalination technologies using renewable energy sources with life cycle, PESTLE, and multi-criteria decision analyses.Water 13, 2023 (2021).
Article Google Scholar
Roy, P., Rao, I. N., Martha, T. R. & Kumar, K. V. Discharge water temperature assessment of thermal power plant using remote sensing techniques. Energy Geosci. 3, 172–181 (2022).
Article Google Scholar
Multi effect distillation. AquaSwiss http://aquaswiss.eu/desalination-solutions/multi-effect-distillation/ (2016).
Multiple Effect Distillation (MED). Veolia https://www.veoliawatertechnologies.com/asia/en/technologies/multiple-effect-distillation-med (2023).
Dresp, S. et al. Direct electrolytic splitting of seawater: activity, selectivity, degradation, and recovery studied from the molecular catalyst structure to the electrolyzer cell level. Adv. Energy Mater. 8, 1800338 (2018).
Article Google Scholar
Dresp, S., Dionigi, F., Klingenhof, M. & Strasser, P. Direct electrolytic splitting of seawater: opportunities and challenges. ACS Energy Lett. 4, 933–942 (2019).
Article CAS Google Scholar
Hauch, A. et al. Recent advances in solid oxide cell technology for electrolysis.Science 370, eaba6118 (2020).
Article CAS PubMed Google Scholar
Taibi, E., Blanco, H., Miranda, R. & Carmo, M. Green Hydrogen Cost Reduction (International Renewable Energy Agency, 2020).
SOEC Topsoe https://www.topsoe.com/our-resources/knowledge/our-products/equipment/soec#:~:text=The%20TOPSOE%E2%84%A2%20SOEC%20electrolyzer,and%20oxygen%20(O2) (2022).
Smit, R., Whitehead, J. & Washington, S. Where are we heading with electric vehicles? Air Qual. Clim. Change 52, 18–27 (2018).
Google Scholar
Babarit, A. et al. Techno-economic feasibility of fleets of far offshore hydrogen-producing wind energy converters. Int. J. Hydrog. Energy 43, 7266–7289 (2018).
Article CAS Google Scholar
Heidari, S. Economic Modelling of Floating Offshore Wind Power. MSc thesis, Mälardalen Univ. (2016).
ERA5 (European Centre for Medium-Range Weather Forecasts, 2021); https://www.ecmwf.int/en/forecasts/datasets/reanalysis-datasets/era5
Salmon, N. & Bañares-Alcántara, R. A global, spatially granular techno-economic analysis of offshore green ammonia production. J. Clean. Prod. 367, 133045 (2022).
Article CAS Google Scholar
Wiser, R. et al. Expert elicitation survey predicts 37% to 49% declines in wind energy costs by 2050. Nat. Energy 6, 555–565 (2021).
Article Google Scholar
Ammonia Fertilizer Market and Price Analysis (S&P Global, 2022); https://ihsmarkit.com/products/fertilizers-ammonia.html
Garcia, L. DTN fertilizer outlook. Progressive Farmer https://www.dtnpf.com/agriculture/web/ag/crops/article/2022/03/15/russia-ukraine-war-drives-world (2022).
Ammonia Market Volatility: Record Prices and an Extended Period of Black Sea Supply Disruption—What Does This Mean for New Pricing Mechanisms? (Argus Media, 2022); https://view.argusmedia.com/rs/584-BUW-606/images/FER-White%20Paper%20Ammonia%20Market%20Volatility.pdf
Crozier, C. & Baker, K. The effect of renewable electricity generation on the value of cross-border interconnection. Appl. Energy 324, 119717 (2022).
Article Google Scholar
Projects. Oceans of Energy https://oceansofenergy.blue/projects/ (2021).
Hill, J. S. Sunseap completes offshore floating solar farm in Straits of Johor. Renew Economy https://reneweconomy.com.au/sunseap-completes-offshore-floating-solar-farm-in-straits-of-johor/ (2021).
Golroodbari, S. Z. & van Sark, W. Simulation of performance differences between offshore and land-based photovoltaic systems. Prog. Photovolt. Res. Appl. 28, 873–886 (2020).
Article Google Scholar
Golroodbari, S. Z. M. et al. Pooling the cable: a techno-economic feasibility study of integrating offshore floating photovoltaic solar technology within an offshore wind park. Sol. Energy 219, 65–74 (2021).
Article Google Scholar
Driscoll, H., Salmon, N. & Bañares-Alcántara, R. Technoeconomic valuation of offshore green ammonia production using tidal and wind energy in the Pentland Firth. In Symposium on Ammonia Energy (University of Orléans, 2022).
Farr, H., Ruttenberg, B., Walter, R. K., Wang, Y.-H. & White, C. Potential environmental effects of deepwater floating offshore wind energy facilities. Ocean Coast. Manage. 207, 105611 (2021).
Article Google Scholar
Lindeboom, H. et al. Short-term ecological effects of an offshore wind farm in the Dutch coastal zone; a compilation. Environ. Res. Lett 1341, 35101–35113 (2011).
Article Google Scholar
Van de Ven, D.-J. et al. The potential land requirements and related land use change emissions of solar energy. Sci. Rep. 11, 2907 (2021).
Article PubMed PubMed Central Google Scholar
Ottinger, M. & Kuenzer, C. Spaceborne L-band synthetic aperture radar data for geoscientific analyses in coastal land applications: a review. Remote Sens. 12, 2228 (2020).
Article Google Scholar
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This work was supported financially by the Rhodes Trust.
Department of Engineering Science, University of Oxford, Oxford, UK
Nicholas Salmon & René Bañares-Alcántara
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Both authors contributed to the conceptualization of the research. N.S. performed the analysis and led the writing of the manuscript. R.B.-A. provided input and helped to write the manuscript.
Correspondence to René Bañares-Alcántara.
The authors declare no competing interests.
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Salmon, N., Bañares-Alcántara, R. Offshore green ammonia synthesis. Nat. Synth (2023). https://doi.org/10.1038/s44160-023-00309-3
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Received: 06 November 2022
Accepted: 31 March 2023
Published: 01 June 2023
DOI: https://doi.org/10.1038/s44160-023-00309-3
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